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POLYTONE®

Phenol Formaldehyde and Phenolic Resin

About POLYTONE® AP & PF SERIES -PHENOLIC RESINS

Polyols & Polymers Pvt. Ltd. via its POLYTONE® range of resins offers a broad range of technical resins specifically designed for the needs of manufacturing of paints, coatings, varnishes, inks, cable insulation, wire enamels, can coatings, epoxy diluents etc.

POLYTONE®
Wire Enamel
Cable Insulation
Paints
Inks & Varnish
Antifreeze Polyamide Inks
Spar Coatings Weather Resistant
Epoxy Diluents Can Coatings
Thermoplastic
Thermosetting
Composites Refractory
Abrasives Emry Wheels
Contact Adhesive Rubber Adhesive
AP 108 EL PtBP Resol
AP 109 EL PtBP Resol
AP 110 EL PtBP Resol
AP 120 E PtBP Novolak
AP 1201 E PtBP Novolak
PF 132 PF Novolak
PF 420 PF Novolak
PF 425 PF Novolak
PF 200 2 Part PF Novolak
PF 201 2 Part PF Novolak

Properties

Product Name POLYTONE® Thermoset Thermoplastic Alkyl Phenol Based Pure Phenol Based 2 Component
AP 108/9/10 EL
AP 120E/1201E
AP 132/PF 132
PF 420/425
PF 200/201 2 Component ✔ + Catalyst

Type

Heat Reactive/Reactive

Alkylphenol Formaldehye

Chemistry POLYTONE® AP 108/109/110 EL

Thermosetting

PtBP Formaldehye

PtBP Resin

Tert Butyl Phenol

Toluene Free

Phenolic Resin Type

Resol

Resole

Non Reactive Thermoplastic Pure Phenolic Resins

Type

Non Heat Reactive

Thermoplastic

Chemistry : POLYTONE® AP 120E/AP 1201E

Alkyl Phenol Formaldehyde

PtBP Resin/Butyl Phenol

Para Tert Butyl Phenol Resin

Chemistry: POLYTONE® AP 132/ 1321/PF 132/PF 420/PF 425

Phenol Formaldehdye

Unmodified Phenolic Novolak

Chemistry: POLYTONE® PF 200/201

2 Component Phenol Formaldehyde Resin

Moulding Powder

Phenolic Resin Type

Novolak

Heat Reactive Thermosetting Phenolic Resins

The addition of high heat resistance POLYTONE® AP 108/109/110 substantially increases adhesion to substrate. It helps lower initial viscosity and hence improves flow ability of formulation. Because of its reactivity, adhesion properties and heat resistant it has also found application in varnishes, insulation coatings, printing inks.

Can be used in formulation of hard ink resins and coating with chemical resistance. In formulation of medium & long oil exterior and interrior varnishes and spar varnises for deck and floor.

Alkyl Phenol Resins/Speciality Grades/Heat Resistant Grades
  POLYTONE® AP 108 EL POLYTONE® AP 109 EL POLYTONE® AP 110 EL
Chemical Classifiction Butyl Phenol (PtBP) Formaldehyde Resol Resin
Color (Gardner) 60% in Toluene 6 MAX 6 MAX 6 MAX
Softening Point (Ball & Ring) 110°C – 125 °C 95°C – 110 °C 110°C – 120 °C
Melting Point (Capillary) 75°C – 90 °C    
Viscosity (B4 Ford Cup @ 30°C) 80°C – 130 Sec (60% Soln in Toluene) 35 – 70 Sec (60% Soln in Toluene) 35 – 75 Sec (60% Soln in Toluene)
Methylol Content 8 – 13 % 10 – 14 % 10 – 14 %
Moisture Content ≤ 0.5 % ≤ 0.5 % ≤ 0.5 %
Characteristics
  • High Heat Resistance
  • Non Phasing
  • Excellent Green Tack
  • Medium Open Time
  • Light Color
  • Toluene Free Grade Available 109 XD
  • Good Heat Reistance
  • Average Open Time
  • Storage Stability
  • Toluene Free Grade Available 110 XD
Solubility Resins are soluble in aromatic hydrocarbon solvents , chlorinated hydrocarbons , ketones and esters etc.
Application/Industry Formulation of inks with chemical resistance. Medium and long oil exterior oil varnishes and spar coatings
Manufacture of coil coatings, cable insulation and high-performance coatings
Manufacture of polychloroprene rubber adhesives with high heat resistance.
*Test Methods available on request

Suggested Formulation for High Performance Coating

Component Ratio
Solvent 100 Parts
Polyester
Polyester Imide
25 – 35 Part
Polyamide Imide  
Stabilizer 1-2 Parts
Anti oxidant 1-2 Parts
POLYTONE® AP 108/109/110 4-5 Parts
*Test Methods available on request
Non-Reactive Thermoplastic Pure Phenolic Resins

POLYTONE® AP 1201 E and AP 120 E are a non heat reactive thermoplastic phenolic resin with excellent alcohol.

It is quick drying, has excellent color retention and is resistant to weathering, alkalis, water and abrasion. It is designed to develop high tack levels in rubber compounds which are used in tyre construction and mechanical goods.

POLYTONE® AP 1201 E and AP 120 E finds its use in tung-oil based varnishes processed at 450°C.
POLYTONE® AP 1201 E and AP 120 E will add surface harness to polyamide-based inks.

Phenolic Resins /Tackifier / Tackifying/Insulating/Anti-Freeze For Flexo Ink
  POLYTONE® AP 1201 E POLYTONE® AP 120 E
Chemical Classification Pure Phenolic Resin (Novolak) Pure Phenolic Resin (Novolak)
Type Non Heat Reactive /Tackifying Thermoplastic Non Heat Reactive /Tackifying Thermoplastic
Colour Light Reddish Brown Pale Yellow/Light Reddish Brown
Colour Gardner (60% Soln in Xylene) 12 Max 8 Max
Softening Point (Ball & Ring) 135 – 145 °C 150 – 165 °C
Acid Value 100 mg KOH/ g resin (Max) 1100 mg KOH/ g resin (Max)
Characteristics
  • PtBP/Butyl Phenol Based
  • Good Buliding Tack
  • Excellent Compatibility with Synthetic & Natural Rubbers
  • Blends Easily with Rubber Stock
  • Chemical Resistance in Exterior Coatings
  • Increases Open time of CR Adhesives
  • High Melting Point and Tg
Solubility These are oil soluble phenolic resin. It has complete solubility in all vegetable oils, aromatics, ketones soluble in esters, ketones, aromatic and aliphatic chlorinated hydrocarbons. oil It has limited solubility in aliphatic. Insoluble in alcohols.
Benefits Excellent compatibility in synthetic and natural rubbers. Blends easily into rubber stocks These shall provide resistance against weather, alkali, water and abrasion
Application/ Industry Tyre /Tire Building, Conveyor Belts, Rubber Hose, Rubber Lining, Rubber Mats, Rubber Sheets, Reinforced Rubber, Fabric Lined Rubber, Rubber Adhesives. Weather resistant finishes, Spar Varnishes, Cold-Mix Varnishes
*Test Methods available on request
Non-Reactive Thermoplastic Phenol Formaldehyde Resins

Non-Reactive Thermoplastic Phenol Formaldehyde Resins

POLYTONE® Resins which are on unmodified phenols provides higher hardness compared to other products
They are designed to give a consistent performance as a reinforcing or binder or base resin. There are used as a reinforcing resin in tire beads, shoe soles, apex strips and co-extruded window profiles

POLYTONE® PF 132 can be used as an epoxy-phenolic co reactant in wide range of epoxy co reactant applications like laminates, adhesives and coatings

POLYTONE® PF 132 can also be used in varnishes, insulations, inks and coatings

Phenolic Resins /Binder/ Reinforcing
  POLYTONE® AP 132 POLYTONE® AP 1321 POLYTONE® PF 132
Chemical Classification Phenol Formaldehyde Resin (Novolak) Phenol Formaldehyde Resin (Novolak) Phenol Formaldehyde Resin (Novolak)
Type Non Heat Reactive / Thermoplastic Non Heat Reactive / Thermoplastic Non Heat Reactive / Thermoplastic
Colour Pale Yellow/light Reddish Brown Pale Yellow/light Reddish Brown Pale Yellow/light Reddish Brown
Softening Point (Ball & Ring) 110 – 116 °C 90 – 100 °C 100 – 116 °C
Methylol Content - 1.0% Max -
Free Phenol 1.0% Max 1.0% Max 0.50% Max
Ash Content 1.0% Max 1.0% Max 0.02% Max [@850°C]
Characteristics
  • Reinforces Compounds with Synthetic & Natural Rubbers
  • Suited for Tire Beads
  • Chip Resistance
  • Abrasion Resistance
Solubility Soluble in esters, ketones, aromatic and aliphatic chlorinated hydrocarbons.Insoluble in higehr alcohols
Application/Industry Used as a reinforcing resin in tire beads, shoe soles, apex strips and co-extruded window profiles. Can be used as an epoxy-phenolic co reactant in wide range of epoxy co reactant applications like laminates, adhesives and coatings Can also be used in varnishes, insulations, inks and coatings
*Test Methods available on request
Low Viscosity Thermoplastic Phenol Formaldehyde Resins

Low Viscosity Thermoplastic Phenol Formaldehyde Resins

POLYTONE® PF 425 and POLYTONE® PF 420 are Non Heat Reactive/Thermoplastic Phenol –Formaldehyde Novolak Resins POLYTONE® PF 420 is a high purity Non Heat Reactive/Thermoplastic Phenol – Formaldehyde Novolak Resin with low softening point. POLYTONE® PF 425 and POLYTONE® PF 420 can be used as an epoxy-phenolic co reactant in wide range of epoxy co-reactant applications like laminates, adhesives and coatings POLYTONE® PF 425 and POLYTONE® PF 420 can also be used in varnishes and inks

Phenolic Resins /Binder/ Reinforcing/Epoxy Co Reactant
  POLYTONE® PF 425 POLYTONE® PF 420
POLYTONE® PF 420 Phenol Formaldehyde Resin (Novolak) Phenol Formaldehyde Resin (Novolak)
Type Non Heat Reactive /Thermoplastic Non Heat Reactive /Thermoplastic
Colour Pale Yellow/Light Reddish Brown Pale Yellow/Light Reddish Brown
Softening Point (Ball & Ring) 110 – 120 °C 80 – 90 °C
Free Phenol 5% 2%
Characteristics
  • Reinforces Compounds with Synthetic & Natural Rubbers
  • Chip Resistance
  • Abrasion Resistance
Solubility POLYTONE® PF 425/420 is soluble in alcohols, esters, ketones, aromatic and aliphatic chlorinated hydrocarbons.
Application/Industry Tyre /Tire Building, Conveyor Belts, Rubber Hose, Rubber Lining, Rubber Mats, Rubber Sheets, Reinforced Rubber, Fabric Lined Rubber, Rubber Adhesives.
POLYTONE® PF 425 and POLYTONE® PF 420 can be used as an epoxy-phenolic co reactant in wide range of epoxy co-reactant applications like laminates, adhesives and coatings
POLYTONE® PF 425 and POLYTONE® PF 420 can also be used in varnishes and inks
*Test Methods available on request
2 Component Phenol Formaldehyde with Catalyst / Hexa

2 Component Phenol Formaldehyde with Catalyst / Hexa

POLYTONE® PF 200/201 are Non Heat Reactive/Thermoplastic Phenol – Formaldehyde Novolak Resins. These are 2 step resin containing Hexa.

COATINGS: Cured phenolic resins demonstrate exceptional chemical resistance. Railroad cars, storage tanks and heat transfer equipment are coated using phenolic resins as part of baked phenolic coating systems.

COMPOSITES: Phenolic resins are the polymer matrix of choice in composite products especially when meeting high flame, smoke and toxicity (FST) properties. Phenolic resins provide for excellent strength at elevated temperatures in a variety of environments and are compatible with a multitude of composite fibers and fillers. Multiple applications benefit by using phenolic resins in the following composite part manufacturing processes:

REFRACTORY: High carbon yield, wear resistance, and excellent particle wetting and bonding properties make phenolic resins ideal for refractory products.

Phenol Formaldehye Resin/2 Component Resin
  POLYTONE® PF 200 POLYTONE® PF 201
Chemical Classification Phenol Formaldehyde Resin with Hexa Phenol Formaldehyde Resin with Hexa
Type Heat Reactive/2 Step mixed with Hexa Heat Reactive/2 Step mixed with Hexa
Colour Cremish Yellow Cremish Yellow
Melting Point (Capillary) 75° C – 90 ° C 70° C – 85 ° C
Inclined Plate Flow @ 125° C 30 – 35mm 30 – 45mm
Hot Plate Cure @ 150° C 75 – 100 seconds 40 – 65 seconds
Sieve Analysis (200 Mesh) 90 - 95% Min 96 – 99% Min
Hexa Content 9 – 10 % 7.5 – 8.5 %
Free Phenol 2 % Max 2 % Max
Characteristics
  • Reinforces Compounds with Synthetic & Natural Rubbers
  • Chip Resistance
  • Abrasion Resistance
Solubility POLYTONE® PF 200/201 is soluble in alcohols, esters, ketones, aromatic and aliphatic chlorinated hydrocarbons.
Application/Industry Tires and technical rubber goods use straight phenolic novolac resins as reinforcing agents.
Abrasives, Emry Wheels, Composites, Refractory, Cured phenolic resins demonstrate exceptional chemical resistance as coatings
*Test Methods available on request
POLYTONE®
Wire Enamel
Cable Insulation
Paints
Inks & Varnish
Antifreeze Polyamide Inks
Spar Coatings Weather Resistant
Epoxy Diluents Can Coatings
Thermoplastic
Thermosetting
Composites Refractory
Abrasives Emry Wheels
Contact Adhesive Rubber Adhesive
AP 108 EL PtBP Resol              
AP 109 EL PtBP Resol              
AP 110 EL PtBP Resol              
AP 120 E PtBP Novolak            
AP 1201 E PtBP Novolak            
PF 132 PF Novolak              
PF 420 PF Novolak                  
PF 425 PF Novolak                  
PF 200 2 Part PF Novolak                  
PF 201 2 Part PF Novolak                  

POLYTONE® Range of Phenolic resin has a wide array of application across industries. The reactive phenolic resins finds in application applications like laminates, adhesives and coatings, Modified Phenolic Novolak like the POLYTONE® AP 120E 1201E are used in varnishes, insulations, inks and coatings

  • POLYTONE® PF 425 and POLYTONE® PF 420 can be used as an epoxy-phenolic co reactant in
  • Wide range of epoxy co-reactant applications like laminates, adhesives and coatings
  • POLYTONE® PF 425 and POLYTONE® PF 420 can also be used in varnishes and inks.
  • Tires and technical rubber goods use straight phenolic novolac resins like POLYTONE® PF 132/1321 as reinforcing agents.

Cured phenolic resins Iike 2 component PF 200 and 201 demonstrate exceptional chemical resistance as coatings , Abrasives, Emry Wheels, Composites, Refractory.

  • Available in 25Kg HDPE Line KRAFT Paper Bags with Anti-Static Liner or 25Kg HDPE Bags.
  • Choice of ISPM 15 Standard Heat Treated/Fumigated Pallets or Plastic Pallets.
  • Individual pallets must NOT be double stacked – pastilles/lumps are likely to agglutinate.
  • Properties are not affected by agglutination.
  • Phenolic Resins tend to discolor over time.
  • Can be stored up to 12 months at temperatures below 35 °C.

Please follow advice and information provided in MSDS. Protective clothing & workplace hygiene measure must be observed at all times.

Detailed MSDS available on request.

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